It covers:
1) Kodiak Tower/Ground
2) Two Anchorage Center sectors (Low and High) from a transmitter in Kodiak.
132.65 is high-altitude enroute and 125.1 is Alaska-Alaska low enroute traffic.
On 132.65 you will hear international traffic with hand-offs to Magadan and Vancouver. It will be rare to hear the aircraft on center. Center simulcasts on transmitters all over the state so you will hear them talking to aircraft far away which we can't hear.